Spectrofluorometric determination of trace amounts of terbium with 4-chlorosalicylic acid, EDTA, and cetyltrimethylammonium bromide.
نویسندگان
چکیده
The quadruple complex formed by terbium with 4-chlorosalicylic acid (CSA), EDTA and cetyltrimethylammonium bromide (CTMAB) has been used for the sensitive spectrofluorometric determination of terbium in mixed rare earths. The effect of the experimental conditions on the fluorescence intensity was defined. Under the optimum conditions selected, the fluorescence intensity was linear with the terbium concentration in the range of 3.0 x 10(-8)-1.0 x 10(-5) mol/L with a detection limit of 8.0 x 10(-9) mol/L (S/N = 3). It has been satisfactory for the determination of terbium in mixed rare earths with good recovery.
منابع مشابه
Simple spectrofluorometric determination of p-aminobenzoic and p-aminosalicylic acids in biological fluids by use of terbium-sensitized luminescence.
A novel, sensitive, and selective method has been developed for determination of p-aminobenzoic (PABA) and p-aminosalicylic (PAS) acids in the N-benzoyl-L-tyrosyl-PABA/ PAS test. PAS is measured as a ternary complex with terbium and EDTA (lambda(ex) = 324 nm, lambda(em) = 546 nm) in alkaline aqueous solution (pH approximately 12.6), whereas both compounds (PABA and PAS) are measured as ternary ...
متن کاملIndirect determination of trace amounts of fluoride in natural waters by ion chromatography: a comparison of on-line post-column fluorimetry and ICP-MS detectors.
An alternative method for the determination of trace levels of fluoride in drinking and sea-water samples is presented. It is based on the formation of the aluminium monofluoride complex in excess of Al3+ and separation of the two species formed (AlF2+ and Al3+) in a small (5 cm long, CG2) ion exchange guard column. The final determination is accomplished by both ICP-MS specific detection and p...
متن کاملIon Pair Dispersive Liquid-Liquid Microextraction for the Determination of Trace Amounts of Copper(II) in Soil, Multivitamin Tablet, Tea and Water Samples Using Flame Atomic Absorption Spectrometry
Ion pair dispersive liquid- liquid microextraction (IP-DLLME) method combined with flame atomic absorption spectrometry was proposed for the determination of trace amounts of copper(II). By using pyrocatechol violet as chelating agent and cetyltrimethyl ammonium bromide as an ion pairing agent, the trace amount of copper(II) was extracted in chloroform. The factors influencing the formation cop...
متن کاملDETERMINATION OF ULTRA-TRACE AMOUNTS OF COBALT BY ADSORPTIVE DIFFERENTIAL PULSE VOLTAMMETRY USING ACDA (2-AMINOCYCLOPENTENE- 1-DITHIOCARBOXYLIC ACID)
The present work describes a selective, rapid and sensitive method for the determination of cobalt using the adsorptive differential pulse voltammetry technique. The method is based on the accumulation of Co(II) complex with 2-aminocyclopentene-1-dithiocarboxylic acid on a hanging mercury drop electrode, followed by measurement of the current of the adsorbed complex. The effects of experimental...
متن کاملHigh-Sensitive and Selective Liquid Membrane Electrode for Direct Determination of Trace Amounts of Chromium
N-(2H-[1,2,4]thiadiazolo[2,3-a]pyridine-2-ylidene)benzamide was used as a selective sensing material in the PVC membrane to construction of a new chromium ion selective electrode. This liquid membrane electrode worked well with a Nernstian response of 19.7 ±0.4 mV decade-1 of Cr(III) in a wide dynamic concentration range of 8.0× 10-6-1.0×10-1 M. The electrode had relatively short response time ...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
- Analytical sciences : the international journal of the Japan Society for Analytical Chemistry
دوره 19 6 شماره
صفحات -
تاریخ انتشار 2003